a)
plecam de la legea gazelor ideale
PV = nRT ; P= 4 atm, V= 410 mL = 0,41 L
T= 273+127oC = 400 K
n = nr.moli = m/M, M=masa molara alcan
=> PVM = mRT => M = mRT/PV
= 2,9x0,082x400/4x0,41 = 58 g/mol
Fm.generala.alcani = CnH2n+2 => M= 14n+2 g/mol
=> 14n+2 = 58 => n = 4 => C4H10, butan
CH3−CH−CH3
I
CH3
b)
C4H10 + 13/2O2 --> 4CO2 + 5H2O
c)
nr.moli = n = V/Vm
=> n = 44,8/22,4 = 2 kmoli
Q.cal = nΔHcomb.x1000/22,4
=> 45613 = 2ΔHcomb.x44,65
=> ΔHcomb. = 510,8 kj/mol